Stabilization of a given type of 3d-metal-centered cage complexes via encapsulation and/or hydrogen abstraction

Alexander S. Chuprin,Anna V. Vologzhanina,Pavel V. Dorovatovskii,Yulia H. Budnikova,Vera V. Khrizanforova,Artem S. Bogomyakov,Matvey V. Fedin,Valentin V. Novikov,Yan Z. Voloshin

Inorganic Chemistry Communications（2024）

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摘要

Template condensation of nioxime as a chelating synthon and tolylboronic acid as a cross-linking agent in the presence of M(II) or M(III) salts (M = Fe, Mn) gave the regular metal(II) clathrochelates. That with Cr(II) or Cr(III) salts afforded the stable chromium(III) macrobicyclic anion-radical with two alicyclic and one ortho-benzoquinonedioximate chelate fragments.

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关键词

Macrocyclic compounds,Clathrochelates,Cage complexes,3d-metal complexes,Ligand reactivity

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