Fundamental Study on Recovery of Spilled Oil by Magnetic Pickering Emulsification

Heavy oil spills from stranded oil tankers are a global problem. The recovery of spilled oil must have a low environmental impact and must be capable of processing large quantities at high speeds. In this study, we investigated the application of magnetic separation for the recovery of spilled oil. Pickering emulsions were formed by heavy oil and magnetite, and recovery was carried out using a drum-type permanent magnet. Pickering emulsions were successfully formed by stirring heavy oil A and magnetite, and magnetic separation experiments showed that up to 90% of the heavy oil A could be recovered. To recycle magnetite, a small amount of heavy oil was added to the recovered Pickering emulsions, and then a strong magnetic field of a superconducting bulk magnet was applied, which resulted in easy solid-liquid separation. The possibility of recycling magnetite after separation was also demonstrated. Finally, a small-scale system using drum-type permanent magnets was developed, and magnetic separation experiments were performed. The results showed that approximately 77% of the heavy oil A could be recovered. Particle trajectory simulations also demonstrated the recoverability of heavy oil at the sea surface. (c) 2024 Institute of Electrical Engineers of Japan. Published by Wiley Periodicals LLC.