Unusual photoinduced crystal structure dynamics in TaTe₂ with double zigzag chain superstructure

Abstract Transition metal dichalcogenides with superperiodic lattice distortions have been widely investigated as the platform of ultrafast structural phase manipulations. Here we performed ultrafast electron diffraction on room-temperature TaTe2, which exhibits peculiar double zigzag chain pattern of Ta atoms. From the time-dependent electron diffraction pattern, we revealed a photoinduced change in the crystal structure occurring within <0.5 ps, though there is no corresponding high-temperature equilibrium phase. We further clarified the slower response (~1.5 ps) reflecting the lattice thermalization. Our result suggests the unusual ultrafast crystal structure dynamics specific to the non-equilibrium transient process in TaTe2.