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A novel approach to obtain 3-amino-1-benzothiophene-2-carbonitriles

Dmitry S. Ivanov,Anatolii I. Sokolov,Alexander Yu. Smirnov,Mikhail S. Baranov

Chemistry of Heterocyclic Compounds（2024）

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Abstract
A simple one-step protocol for the synthesis of 3-amino-1-benzothiophene-2-carbonitriles from commercially or synthetically readily available S-(cyanomethyl) O-ethyl carbodithionate and 2-fluorobenzonitriles was developed.
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3-amino-1-benzothiophene-2-carbonitriles,S-(cyanomethyl) O-ethyl carbodithionate,S-(cyanomethyl) O-ethyl xanthate,2-fluorobenzonitriles,intramolecular condensation
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