Magnetic anisotropy in octahedral Dy(iii) and Yb(iii) complexes
DALTON TRANSACTIONS（2024）
摘要
New organophosphate complexes [Ln(dippH)(3)(dippH(2))(3)](H2O)(6), (Ln = Dy, Yb and Y; dippH(2) = 2,6-diisopropylphenyl phosphate), displaying octahedral coordination geometry around the metal ion, exhibit unusual slow relaxation of magnetisation, which is investigated through experimental studies and ab initio CASSCF calculations.
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