Thermoelastic Properties of Fe³⁺-Rich Jeffbenite and Application to Superdeep Diamond Barometry

Jeffbenite (Mg3Al2Si3O12) is a tetragonal phase found in so far only in superdeep diamonds, and its thermoelastic parameters are a prerequisite for determining entrapment pressures as it is regarded as a potential indicator for superdeep diamonds. In this study, the thermoelastic properties of synthetic Fe3+-jeffbenite were measured up to 33.7 GPa and 750 K. High-temperature static compression data were fitted, giving (partial derivative K-T0/partial derivative(T))(P) = -0.0107 (4) GPa/K and alpha(T) = 3.50 (3) x 10(-5) K-1. The thermoelastic properties and phase stability are applied to modeling isomekes, or P-T paths intersecting possible conditions of entrapment in diamond. We calculate that under ideal exhumation, jeffbenite entrapped at mantle transition zone conditions will exhibit a high remnant pressure at 300 K (P-inc) of similar to 5.0 GPa. Elastic geobarometry on future finds of jeffbenite inclusions can use the new equation of state to estimate entrapment pressures for this phase with still highly uncertain stability field in the mantle.