Insights into structural and functional regulation of chalcopyrite and enhanced mechanism of reactive oxygen species (ROS) generation in advanced oxidation process (AOP): A review

Chalcopyrite, renowned for its distinctive mixed redox-couple characteristics, exhibits excellent electron transfer properties both on its surface and within its crystal structure. This unique characteristic has attracted significant attention in various fields, including optics, electronics, and magnetism, as well as demonstrated remarkable catalytic efficacy in the environmental field. The rapid and effective electron transfer capability of a catalyst is crucial for advanced oxidation processes (AOPs). However, the performance of CuFeS2 in AOPs is hindered by its low electron transfer efficacy. This review aims to summarize the key steps and mechanisms of chalcopyriteinduced AOPs and provide strategies for enhancing effective electron transfer efficacies by controlling the structure and function of synthetic/natural chalcopyrite. These strategies include enhancing the catalytic performance of chalcopyrite and constructing composites to enhance catalytic activity (e.g., chelating agents, heterojunctions). Additionally, the factors influencing the generation of reactive oxygen species in chalcopyriteinduced AOPs are investigated, such as the types and properties of oxidants (e.g., H2O2, peroxymonocarbonate), the microstructure of catalysts, and reaction conditions in catalytic systems (e.g., pH values, dosage, temperature). Future perspectives on the applications of chalcopyrite are presented at the end of this paper. Overall, this review assists in narrowing the scope of chalcopyrite studies in AOPs and aids researchers in optimizing synthetic/natural catalysts for contaminant treatment.