Hydrogen production from plastic waste: A comprehensive simulation and machine learning study

Gasification, a highly efficient method, is under extensive investigation due to its potential to convert biomass and plastic waste into eco-friendly energy sources and valuable fuels. Nevertheless, there exists a gap in comprehension regarding the integrated thermochemical process of polystyrene (PS) and polypropylene (PP) and its capability to produce hydrogen (H-2) fuel. In this study a comprehensive process simulation using a quasi-equilibrium approach based on minimizing Gibbs free energy has been introduced. To enhance H-2 content, a water-gas shift (WGS) reactor and a pressure swing adsorption (PSA) unit were integrated for effective H-2 separation, increasing H-2 production to 27.81 kg/h. To investigate the operating conditions on the process the effects of three key variables in a gasification reactor namely gasification temperature, feedstock flow rate and gasification pressure have been explored using sensitivity analysis. Furthermore, several machine learning models have been utilized to discover and optimize maximum capacity of the process for H-2 production. The sensitivity analysis reveals that elevating the gasification temperature from 500 degrees C to 1200 degrees C results in higher production of H-2 up to 23 % and carbon monoxide (CO). However, generating H-2 above 900 degrees C does not lead to a significant upturn in process capacity. Conversely, an increase in pressure within the gasification reactor is shown to decrease the system capacity for generating both H-2 and CO. Moreover, increasing the mass flow rate of the gasifying agent to 250 kg/h in the gasification reactor has shown to be merely productive in process capacity for H-2 generation, almost a 5 % increase. Regarding pressure, the hydrogen yield decreases from 22.64 % to 17.4 % with an increase in pressure from 1 to 10 bar. It has been also revealed that gasification temperature has more predominant effect on Cold gas efficiency (CGE) compared to gasification pressure and Highest CGE Has been shown by PP at 1200 degrees C. Among the various machine learning models, Random Forest (RF) model demonstrates robust performance, achieving R-2 values exceeding 0.99.