Enhancing heat modification efficiency of Chinese fir wood through fly ash impregnation: A comprehensive evaluation using time-temperature superposition and cluster analysis

Catalytic degradation via fly ash impregnation (Im) has proven effective in reducing the heat modification (HM) temperature required for wood. To accurately gauge the intensity of HM on wood following Im, the physiomechanical properties of Im-HM treated wood were investigated across various treatment conditions (temperature: 80-140 degrees C, duration: 1-4 h, and fly ash concentration: 2-8%), and compared them to conventional HM (CoHM) wood. Two mathematical methods (time-temperature superposition and cluster analysis) were employed to elucidate the relationships between treatment conditions and resulting properties. Results indicated that ImHM treated wood exhibited comparable dimensional stability and visual appearance to CoHM wood, while retaining superior mechanical properties. The acid-catalyzed effect of Im-HM demonstrated significant dependence on treatment temperature, duration, and concentration, providing an avenue to regulate catalytic intensity. Employing the time-temperature superposition principle, master curves for weight percentage loss (WPL), modulus of elasticity (MOE) and anti-swelling efficiency (ASE) were constructed under a reference condition (80 degrees C and 2% concentration), covering processing duration up to 20 hours. These master curves facilitated understanding the relationship between temperature, duration and concentration when evaluating catalytic intensity. Cluster analysis, based on the physiomechanical properties of Im-HM and CoHM wood, offered a clear interpretation of HM intensity. Notably, Im-HM treatment at 140 degrees C for 4 hours with an 8% concentration exhibited HM intensity similar to CoHM treatment at 200 degrees C. Through the integration of timetemperature superposition and cluster analysis, this study assesses Im-HM intensity, providing a valuable reference for the industrial application of Im-HM treatment.