Cu₂ZnSnS₄‐Based Electrode as an Improvement Strategy for Lithium Rechargeable Batteries: A Status Review

Cu2ZnSnS4 (CZTS) is seen as a microstructure electrode due to its high energy density when applied in lithium rechargeable batteries such as lithium‐ion batteries (LIB) and lithium sulfur batteries (LSB). This review provides a systematic observation to evaluate the CZTS electrode capabilities from the perspective of electrode composition and its performance in lithium rechargeable batteries. This review starts by focusing on state‐of‐art lithium rechargeable batteries using common sulfur/sulfide‐based materials reported from literature. The relation between the LSB performance with the active materials ‐ sulfur, binder, solvents, electrolytes, and conducting additive used for lithium sulfide (Li2S) formation required for charge transfer properties is discussed critically. The following section discusses the current progress on CZTS‐based electrode in lithium rechargeable batteries and it is found that the highest capacity obtained with improved interfacial compatibility is 1802 mAh g−1 by hydrothermal techniques using 1 m LiPF6 in EC/EMC/DMC electrolyte. These properties have made sulfide component in CZTS structure as a great substitute to conventional sulfur/sulfide‐based active materials. Therefore, CZTS has become a promising and huge potential electrode in lithium rechargeable batteries.