Hydrophobic modification of walnut shell biomass-derived porous carbon for the adsorption of VOCs at high humidity

Volatile organic compounds (VOCs) often contain water vapor in their exhaust emissions, resulting in the deterioration of the adsorption capacity of activated carbon (AC). A hydrophobic walnut shell biomass-derived AC using polytetrafluoroethylene (PTFE) and polydimethylsiloxane-coated SiO2 (PDMS/SiO2) was developed to improve the selectivity of VOCs under high humidity conditions. These modified ACs were systematically characterized, and dynamic adsorption behaviors of VOCs such as toluene, acetone and their mixtures at the relative humidity (RH) between 0 and 90 % were conducted. The results showed that walnut shell biomassderived AC has large specific surface area (1853 m2/g) and total pore volume (1.27 cm3/g), strong hydrophilicity (water contact angle of 6.3 degrees), abundant oxygen-containing groups (-OH, C--O, C-O) and aromatic rings. The coating of PDMS/SiO2-PTFE reduces the surface area and total pore volume of AC, but it creates a doublelayer rough structure on the AC surface and introduces C-F and Si-O-Si hydrophobic groups, which achieves a water contact angle of 152.8 degrees for 25PSP/AC. The Yoon-Nelson model is suitable to describe the dynamic adsorption process of single- toluene or acetone under dry/humid condition but not suitable for their mixtures. At RH 90 %, PDMS/SiO2-PTFE modified AC significantly increases the adsorption capacity of toluene but is not obviously improved for acetone, which is due to the different polarity of toluene and acetone. PDMS/SiO2-PTFE films on AC have good thermal stability before 500 degrees C and the hydrophobicity does not change after multiregeneration at 200 degrees C. Therefore, PDMS/SiO2-PTFE modified AC has shown great potential as adsorbent to remove the toluene from the humid condition.