The Impact of Polymer Matrix Type On the Optical Properties of Silver Nanocomposites

Nanocomposites materials of silver (Ag) with polyethene oxide, venal polyalcohol and polyvinyl pyrrolidone were synthesized by chemical reduction method using trisodium citrate (TSC) as a reduction agent. Silver based nanocomposites deposited as a film by dropcasting technique on (2x2 cm2) glass substrates. The effect of polymer matrix type on the optical properties (surface plasmon resonance, transmission and direct and indirect bandgap) were investigated. It was observed from the absorption spectra of the various synthesized materials that the type of polymer used in the preparation process significantly influences the location of the plasmonic absorption peak and the amount of the energy gap.