Modeling the Global Water Cycle-The Effect of Mg-Sursassite and Phase a on Deep Slab Dehydration and the Global Subduction Zone Water Budget

We study the interplay of the thermal structure within subducted oceanic slabs together with the stability fields of hydrous phases that control slab dehydration and the amount of water transported into the deeper mantle. We implement different published thermodynamic data for phase A and Mg-sursassite into a model of 56 subduction zones and evaluate the effect of these phases on the global water budget. We modeled vertical fluid fluxes within the slab such that dehydration-derived fluid was allowed to react with fluid-undersaturated rocks in other parts of the slab. The effect of Mg-sursassite on the global water budget is limited, because the Clapeyron slope of this dehydration reaction is steeper than most pressure-temperature trajectories in subduction zones. Two sets of published thermodynamic data for phase A yield significantly different values for the amount of deeply subducted water, ranging between 8 x 108 Tg/Ma and 1.4 x 109 Tg/Ma. In some subduction zones, the differences span several orders of magnitude. The absolute modeled amount of deeply subducted water strongly depends on the depth and intensity of slab mantle hydration, but a comparison of modeled and experimental data indicates that the thermodynamic dataset that yielded higher values is more reliable and should be implemented in future thermodynamic models. Our results show that the stable phases around the choke point as well as the slope and position of the phase A-out reaction influence the deep water release from the slab, but the slope and position of the phase A dehydration reaction mainly control the recycling of water into the deep mantle. Water on our planet is constantly exchanged between the oceans and the interior of the Earth. This happens at subduction zones where hydrated oceanic crust is sinking into the Earth's mantle, thus bringing water to depths exceeding 300 km. We quantify this amount of water that is globally recycled into the deeper Earth in subduction zones through computer models that combine the temperature structure of the subducted rocks with the stability of hydrous phases. Knowledge about the global water budget is important to quantify the Earth's total water amount, to understand the water release from the subducting oceanic plate, and to interpret sea level changes in Earth's history. We compared thermodynamic datasets for two minerals, namely Mg-sursassite and phase A, in the oceanic plate that can transfer large amounts of water into the deeper Earth. Our thermodynamic models show that the stability of phase A in the down going oceanic plate controls much of the recycled water in most subduction zones. Mg-sursassite has a limited influence on the global amount of subducted water Mg-sursassite can transfer water to depths of up to 250 km and lead to deep dehydration and water release from the slab The Clapeyron slope of the phase A dehydration reaction is sub-parallel to many slab P-T paths and mainly controls the deep water subduction