Steam Adsorption Equilibrium Data at 110 C on Activated Carbon, Lewatit VP OC 1065, and CALF-20 Using a Microscale Dynamic Column Breakthrough Apparatus

Steam adsorption equilibrium data is important for many carbon capture applications. However, there is a dearth of concentrated unary equilibrium data for H2O at temperatures greater than 100 degrees C. In this study, unary steam adsorption equilibrium data was measured at 110 degrees C up to approximately 1.0 bar partial pressure with a steam microscale dynamic column breakthrough (mu DCB) apparatus using milligram quantities of adsorbent. These partial pressures are equivalent to those used in industrial carbon capture processes. The construction of the apparatus is detailed, including calibrations and validations, to ensure accurate equilibrium measurement. Three adsorbents were considered in this study: an activated carbon (Calgon BPL), an amine-functionalized polymer (Lewatit VP OC 1065), and a metal-organic framework (CALF-20). Steam adsorbs strongly on all three materials at 110 degrees C. Activated carbon and Lewatit displayed type-3 isotherm shapes, and CALF-20 displayed a type-5 isotherm shape. The 110 degrees C data was compared against H2O equilibrium data collected at 25 degrees C as a function of relative pressure. An in-house dynamic column breakthrough simulator could predict the mu DCB composition breakthrough curves well for all three materials. The data obtained has important process implications and highlights the need to measure steam adsorption data for any proposed carbon capture material.