Effects of silylene ligands on catalytic activity of [PSiP] pincer cobalt(II) chloride for N2 silylation

Min Zhang,Yanhong Dong,Qingshuang Li,Xiaoyan Li,Hongjian Sun

New Journal of Chemistry（2024）

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摘要

Three silyl [PSiP] pincer cobalt(II) chlorides 1 - 3 [(2-Ph2PC6H4)2MeSiCo(Cl)(PMe3)] (1), [(2-iPr2PC6H4)2MeSiCo(Cl)(PMe3)] (2) and [(2-Ph2PC6H4)2MeSiCo(Cl)(LSi:)] (LSi: = {PhC(NtBu)2}SiCl) (3) were synthesized and used as catalysts to study their catalytic activity...

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