Interactions between alkali cations and cyanide-bridged network in A2Co4[Fe(CN)6]3.3 Prussian blue analogues revealed by far-infrared spectroscopy

Maria Dronova,Laura Altenschmidt,Amélie Bordage,Jean-Blaise Brubach,Marine Verseils, Gregory Balthazar,Pascale Roy,Anne Bleuzen

Materials Advances（2024）

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摘要

A series of Prussian Blue Analogues (PBAs) having the chemical formula A2Co4[Fe(CN)6]3.3nH2O (A+ = Na+, Rb+ and Cs+) was investigated by variable temperature far-infrared spectroscopy. Despite the same chemical composition...

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