Radical 1,4-aryl migration enables nickel-catalysed remote cross-electrophile coupling of β-bromo amino acid esters with vinyl triflates

A radical 1, 4-aryl migration enabling cross-electrophile coupling reaction toward remote transalkylation of N-benzyl alanine has been reported. In this strategy, with the occurrence radical-mediated Turce-Smiles rearrangement, the key α-aminoalkyl...