Solid-State Transformations of Active Materials in the Pores of Sulfurized-Polyacrylonitrile Fiber Membranes via Nucleophilic Reactions for High-Loading and Free-Standing Lithium–Sulfur Battery Cathodes

Advanced Fiber Materials(2024)

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Abstract
Sulfurized polyacrylonitrile (SPAN) has emerged as an excellent cathode material for lithium–sulfur batteries (LiSBs), and it addresses the shuttle effect through a solid‒solid reaction. However, the actual sulfur loadings in SPAN often remain below 40 wt
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Key words
Lithium–sulfur batteries,Sulfurized polyacrylonitrile,Cathode–electrolyte interphase,High active material content,Nucleophilic reactions
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