Photoswitching of arylazopyrazoles upon S1 (nπ*) excitation studied by transient absorption and ab-initio molecular dynamics

Till Reichenauer,Marcus Böckmann, Katharina Ziegler,Vikas Kumar,Bart Jan Ravoo, Nikos Dolsinis,Sebastian Schlücker

Physical Chemistry Chemical Physics(2024)

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摘要
Arylazopyrazoles (AAPs) are an important class of molecular photoswitches with high photostationary states (PSS) and long thermal lifetimes. The ultrafast photoisomerization of four water-soluble arylazopyrazoles, all of them featuring an...
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