Formation of paired Ga sites in CHA-type zeolite frameworks via a transcription-induced method.

Takumi Kaneko,Mizuho Yabushita,Ryota Osuga, Yugo Sawada, Kei Sato,Ben Liu,Yoshinao Nakagawa,Kiyotaka Nakajima,Keiichi Tomishige

Chemical communications (Cambridge, England)（2024）

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Abstract

Paired Ga sites represented by the Ga-O-Si-O-Ga sequence were firstly formed intentionally in CHA-type zeolite frameworks via the transcription of pre-formed paired Ga species in a Ga-rich amorphous silica-gallia under seed-assisted hydrothermal conditions. Such paired Ga sites behaved as ion-exchange sites for capturing divalent cation, Co2+.

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