Increasing hydrologic connectivity contributes to browning of northern freshwater

Sustained increments of organic carbon concentrations in northern freshwaters have triggered concerns about the impacts of water browning and raised questions on the underlying mechanisms causing this phenomenon. In addition to the key role played by reduced sulfate deposition, hydrologic mechanisms have been put forward as possible concurrent causes of the observed trends of organic carbon concentrations. How the suggested hydrologic controls act is however still unclear. In this study we analyze long data series (> 30 years) of daily discharge and weekly to biweekly Total Organic Carbon (TOC) concentration for four reference acid-sensitive rivers in Norway, whose locations span the entire length of the country, to clarify hydrologic changes which may be promoting freshwater browning. In all cases we observe stable values of the slopes of double logarithmic relations between concentration and discharge, as well as a steady growth along the years of the intercepts of these relations. These joint observations enable sorting out previously proposed biogeochemical mechanisms for the observed trends of TOC concentrations (i.e., less sulfate deposition versus higher soil temperature). Decreasing ratios of concentration and discharge variability along the years, observed in all watersheds during the autumn season, point at growing stores of organic carbon produced in summer and suggest that the spatial distribution of the sources is becoming more homogeneous. In detail, analyses of the runoff frequency, which is typically higher in wetter and more hydrologically connected watersheds, suggest that sources are more homogeneously connected to streams than before. In fact, increasing trends throughout the years of the runoff frequency, as well as strong relations between runoff frequency and increasing concentrations of aquatic organic carbon, are detected in all cases. More connected sources together with more frequent runoff events, which multiply the chances for the organic carbon to reach streams, may hence contribute to the observed rise of organic carbon concentrations in northern freshwaters.