Evolving Chemistry of Lithospheric Mantle Based on Oxygen Isotope and Trace Element Analyses of Olivines from Mantle Xenoliths across Earth’s History

Oxygen is the most abundant element in the terrestrial mantle and crust. We have recently reported on a 0.2‰ δ18O decrease of continental mantle peridotites from the original primary Bulk Silicate Earth-Moon value of 5.57‰ [1] in the mid-Archean to the Phanerozoic explained by the initiation of surface recycling (linked to intensity and style of plate tectonics) sometime in the Archean. Even small variations in the volatile mass balance are critical in explaining phenomena such as the Great Oxidation Event at ~2.4 Ga that may have mantle origin. As low-δ18O subduction fluids are derived by the dehydration (and potentially oxidation) of low-δ18O interiors of subducted slabs, this work further explores this process to observe temporal changes related to the progressive input of volatile elements and potential lithospheric mantle oxidation. This study presents a record of trace elements measured in same olivines (Li, Na, Al, P, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Ga, Y, Zr) including oxidation-sensitive elemental ratios V/Sc and Zn/Fe for this collection. Prior melt-depletion of mantle peridotites, estimated using bulk Al2O3 content of the xenoliths, increases with age from ~25 to 35%, leading to depletion of Yb, Y, Co, Mn, Ca, P, with smaller effects on the elemental ratios.  We observe significant ranges of V/Sc (0.2-14), Li/Y and other ratios, not related to prior melt depletion that may be linked to subduction-related re-distribution of incompatible elements by subduction [2], and scattered correlation with age and δ18O values. Further trends will be analyzed during the talk after considering craton-specific domains and global trends. This work can potentially contribute to constraining a global mass balance of crustal growth and recycling based on co-variations of isotopes of a major element oxygen and trace elements in the predominant lithospheric reservoir of subcontinental mantle.[1]Bindeman ea, (2022) Nat Comm 13, 3779; [2] Doucet ea, (2020) NatGeosci 13, 511.