Sustainable ultra-strong polyesteramide elastomers with rapid degradation and high resilience

Degradable polymers typically require prolonged exposure to harsh conditions for degradation, but this extended duration and severe treatment often result in incomplete breakdown, leading to the formation of harmful microplastics that pose significant environmental pollution risks. In this work, degradable alternating polyamide hard segments and soft crystallizable segments were combined by amide groups to design thermoplastic biobased polyesteramide elastomers (PEAEs) with customizable properties and rapid degradability. The hard segment of the polymer features an alternating arrangement of amide and ester bonds. This arrangement facilitates the formation of small molecule monomers when the ester bond is broken, preventing microplastic contamination that may arise from incomplete degradation of the hard segment. Additionally, the inclusion of side groups in the soft segment disrupts the crystallization, enhancing its susceptibility to solvent penetration and thereby accelerating the degradation rate. After step-cyclic tensile tests, additional physical cross-linking points were formed in PEAEs to enhance their mechanical strength and elasticity. Furthermore, PEAEs demonstrated outstanding processing capabilities, including compounding, extrusion, pelletization, and spinning. This innovative approach introduces fresh design concepts for the industrial application of bio-based degradable polymers, playing a pivotal role in advancing resource conservation and environmental protection.