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Tailoring Cu immobilized MCM-41-based mesostructured catalysts for selective hydrogenolysis of biomass-derived furfural

Y. Leela Prasad, K. Swamy Sekhar,Raveendra Gundeboyina, Ramakrishna Pothu, M. Vijaya,B. Venkateswara Rao,Rajender Boddula, Rammohanrao Devulapalli,Harisekhar Mitta

Catalysis Communications(2024)

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Abstract
The CuO-supported MCM-41 catalysts were prepared using a simple incipient wet impregnation method. The catalysts were investigated for hydrogenation of furfural to furfuryl alcohol synthesis. Among all the catalysts, the 2.5% CuO/MCM-41 catalyst shows the best catalytic performance with 92.5% conversion and 89% selectivity of furfuryl alcohol at 210 °C. The catalyst also demonstrated a high turnover frequency (TOF) of 154.4 h−1. The 2.5% CuO/MCM-41 catalyst remained stable for up to 20 h during the time on stream.
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Key words
Hydrogenation,Furfural,Furfuryl alcohol,CuO,MCM-41,Sustainability energy & fuels,Green chemistry
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