Synthesis of -Hydroxyselenides via Electrochemical Hydroxyselenenylation of Alkenes with Diselenides and H2O
CHEMISTRYSELECT(2024)
Abstract
A practical electrochemical method for the synthesis of beta-hydroxyselenides has been developed under an external oxidant-free condition at room temperature under air from alkenes with diselenides and H2O. A radical mechanism is proposed for this transformation and the gram-scale reactions demonstrate the practicability of this reaction.
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Key words
beta-hydroxyselenides,diselenides,alkenes,external oxidant-free,electrochemical hydroxyselenenylation
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