Cold deep subduction of Indian continental crust and release of ultrahigh-pressure fluid during initial exhumation: Insights from coesite-bearing eclogite-vein systems in Kaghan Valley, Pakistan

The ultrahigh-pressure (UHP) eclogites from the Kaghan Valley in Pakistan, which formed by the deep subduction of the Indian plate beneath the Asian plate in the Eocene, contain complex metamorphic vein systems (including both isolated veins and vein networks), with mineral assemblages of epidote + quartz + kyanite + phengite +/- omphacite +/- garnet. The investigations on the Kaghan UHP eclogite-vein systems provide important insights into the mechanism and timing of metamorphic dehydration, fluid flow, and fluid-rock interaction in the deeply subducted Indian continental slab as well as the chemical characteristics of slab-derived, aqueous fluids. Abundant lawsonite pseudomorphs, characterized by prismatic aggregates of epidote, kyanite, and quartz porphyroblasts, are first recognized in the Kaghan eclogites. This observation, in combination with the occurrence of coesite pseudomorphs in epidote porphyroblasts as well as the coexistence of epidote and coesite in the eclogite zircon, indicates the previous existence of UHP lawsonite in these eclogites. Petrological studies and phase equilibrium modelling reveal clockwise P-T trajectories for the Kaghan eclogites that are featured by prograde vectors in lawsonite-stability regions with peak conditions of 3.0-3.4 GPa/650-690 degrees C, followed by isothermal decompression and lawsonite breakdown under UHP conditions during the initial exhumation stage. The results of metamorphic evolution, together with in situ epidote and bulk Sr isotopic analyses, indicate that the fluids responsible for vein systems are most likely derived from the breakdown of UHP lawsonite in the eclogites. SIMS U-Pb dating of metamorphic zircons from the eclogites, integrated with the Raman analysis of inclusions in zircons, indicates that the UHP dehydration of eclogites occurred at 46.4 +/- 1.2 and 46.8 +/- 0.9 Ma. Analyses of hydrothermal zircons from the veins yielded slightly younger ages of 44.7 +/- 1.0 and 44.9 +/- 1.4 Ma, which represent the timing of fluid flow and/or vein crystallization during exhumation of the UHP rocks. Mass-balance calculation results, in combination with the vein compositions, show that the fluid flow and fluid-eclogite interaction led to the transfer of Si, Al, Ca, K, and incompatible trace elements from the eclogites into the fluids, from which the vein systems crystallized. This study indicates cold deep subduction of Indian continental crust along low geothermal gradients (6-7 degrees C/km). The UHP fluid liberation and channelized fluid flow occurred during the initial exhumation of the cold Indian slab and are expected to induce the transfer of H2O and incompatible trace elements from the Indian slab to the Asian lithosphere, which potentially contributes to the formation of post-collisional magmas. Moreover, we suggest that metamorphic vein systems in UHP lawsonite eclogites offer important constraints on the occurrence and timing of fast slab exhumation in continental subduction-collision zones.