Cu-doped Ba0.5Sr0.5FeO3- for electrochemical synthesis of hydrogen peroxide via a 2-electron oxygen reduction reaction
ELECTROCHEMICAL SCIENCE ADVANCES(2023)
摘要
Electrochemical synthesis of hydrogen peroxide (H2O2) via a two-electron (2e(-)) oxygen reduction reaction (ORR) has emerged as a sustainable synthesis route compared to the anthraquinone oxidation synthesis process. Ba0.5Sr0.5Fe(1-x)CuxO3-delta perovskite is a particularly interesting electrocatalyst for ORR applications owing to its doping flexibility. In this study, we use experimental and computation approaches to study Ba0.5Sr0.5FeO3-delta with and without copper doping at the B-site for 2e(-) ORR. Our electrochemical measurements in oxygen-saturated alkaline solution show that the selectivity of perovskite electrocatalyst increases from 30% to 65% with (0.05) copper doping in the B-site and the onset potential is decreased. Density functional theory calculations are used to unravel the role of copper in driving high activity and selectivity toward 2e(-) ORR. Site-specific engineering of Ba0.5Sr0.5FeO3-delta by copper doping in the B-site exposed unique adsorption sites with improved activity and selectivity for H2O2 formation.
更多查看译文
关键词
Density functional theory calculations,electrochemical synthesis of hydrogen peroxide,perovskites,two-electron oxygen reduction reaction
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要