Crystal structure of tetrakis(μ-2-hydroxy-3,5-diisopropylbenzoato)bis[(dimethyl sulfoxide)copper(II)]
Acta Crystallographica Section E: Crystallographic Communications(2024)
Abstract
A solution of 2-hydroxy-3,5-bis(1-methylethyl)benzoic acid copper(II) hydrate (C26H34CuO6·xH2O), also known as copper(II) 3,5-diisopropylsalicylate hydrate, in dimethyl sulfoxide (DMSO) affords crystals of tetrakis-3,5-diisopropylsalicylatobis-dimethylsulfoxidodicopper(II), [Cu(II)2(3,5-DIPS)4(DMSO)2], upon evaporation. The structure has an empirical formula of [Cu2(C13H17O3)4(C2H6OS)2] and consists of a centrosymmetric binuclear copper complex surrounded by four 3,5-diisopropylsalicylate ligands. Each copper atom is attached to four oxygen atoms in an almost square-planar fashion, with the addition of a DMSO ligand in an apical position leading to a square-pyramidal arrangement.
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Key words
crystal structure,binuclear copper,3,5-diisopropylsalicylate,dimethyl sulfoxide.
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