Ecological risk assessment, source identification and spatial distribution of organic contaminants in terms of mucilage threat in streams of Çanakkale Strait Basin (Türkiye).

Chemosphere(2024)

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摘要
In this study, the spatial distributions of organic contamination stressors in water of fluvial habitats in the Çanakkale Strait (ÇS) watershed were investigated and the data were assessed in terms of human health and mucilage threat. Seven significant riverine ecosystems flowing into the ÇS were defined in the basin. Water samples were taken in the spring season (2023), when the phytoplankton communities reach their highest densities. Then they were tested for a total of 8 limnological parameters. The Nutrient Pollution Index (NPI) and Water Quality Index (WQI) were applied to assess the comprehensive quality characteristics of waters. The Hazard Quotient (HQ) and Hazard Index (HI) were applied to indicate the prospective non-carcinogenic human health risks of organic stressors. Principal Component Analysis (PCA) and Cluster Analysis (CA) were applied to categorize the investigated habitats and define the sources of investigated contamination parameters. Also, Geographic Information System (GIS) was used to make an effective assessment through visualization. The determined spatial mean values of the measured variables in ÇS watershed as follows: 18.21 °C for temperature, 8.51 mg/L for DO, 4.57 NTU for turbidity, 3.95 mg/L for suspended solids, 1.11 mg/L for NO3-N, 0.012 mg/L for NO2-N; 0.173 mg/L for PO4-P and 2.32 mg/L for BOD. It has been determined that the organic pollution loads and water temperature values of the investigated sub-basins increase from the upstream to the downstream locations and Çanakkale Stream was recorded as the riskiest fluvial habitat for the ÇS watershed. According to the results of health risk assessment indices, non-carcinogenic risks of organic pollutants would not be expected for all age groups.
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