Correction: Effect of Ni dopant on the capacitive behavior of CuS for supercapacitor application

Journal of Materials Science: Materials in Electronics(2024)

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摘要
Metal sulfide nanomaterials are addressed as electrode for supercapacitor applications, but their utilization is constrained due to less stability and poor capacity performance. The doping strategy is a successful method for enhancing the capacitance nature, cyclic stability, and conductivity property. In this investigation, nickel-doped copper sulfide (Ni–CuS) with different concentrations was synthesized by using the facile hydrothermal approach to resolve energy storage issues. A number of approaches are used to evaluate the structure, purity, phases, material composition, textural aspects, and morphology. In comparison to other electrode materials, the Ni 0.007 CuS electrode contains a substantial specific capacitance (C s ) value of 1485.355 F g −1 with an impressive energy density (E d ) of 94.27 Wh Kg −1 as well as power density (P d ) of 338 W Kg −1 . The stability analysis of Ni 0.007 CuS exhibited 92.96% capacitance retention after 5000th GCD cycles with only minor structural degradation, as investigated with X-ray diffraction (XRD). The achieved finding from the electrochemical impedance spectroscopy (EIS) suggested that the Ni 0.007 CuS exhibits the 1.68 Ω charge transfer resistance (R ct ). The two-electrode results show that Ni 0.007 CuS contains a C s of 620 F g −1 and an E d of 128 Wh kg −1 . Our research demonstrates that including of nickel dopant in the form of Ni 0.007 CuS nanoarray enhances the efficiency of charge migration by facilitating a convenient route for the transfer of electrolyte ions. As a result, we conclude that these cathode materials are suitable for use in supercapacitor applications.
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