Luminescent Metal Complexes of Polydentate Azomethine Ligands

The article represents a translated, revised, and updated Section 6.3 of the monograph by A.S. Burlov, V.G. Vlasenko, D.A. Garnovskiy, A.I. Uraev, E.I. Maltsev, D.A. Lypenko, and A.V. Vannikov, Electroluminescent Organic Light-Emitting Diodes Based on Metal Coordination Compounds , Rostov-on-Don: Yuzhn. Fed. Univ., 2015; ISBN 978-5-9275-1469-4 (see Additional Information). This section is dedicated to reviewing the photoluminescence and electroluminescence properties of metal complexes based on bi- and polydentate ligands of the azomethine type (Schiff bases). Many metal complexes of Schiff bases find wide use as luminescent materials. One of the applications of these compounds is the use as emissive layers or dopants for manufacturing OLED. The photo- and electroluminescence properties of a series of the metal complexes with the ligands based on the derivatives of hydroxybenzaldehyde, 2-( N -tosylamino)benzaldehyde, 1‑phenyl-3-methyl-4-formylpyrazol-5-one, and some others are reviewed. The systematic categorization of these compounds extends beyond their photophysical properties to consider the electroluminescence characteristics observed in OLED devices employing them as the basis. By modifying known azomethine-type ligand systems, one can obtain metal complex compounds with exceptional thermal stability, solubility, and quantum efficiency. These characteristics enable their use as luminescent materials in highly efficient OLED devices.