Transesterification of Bis 2-Hydroxyethyl Terephthalate for Production of Bis 4-Hydroxybutyl Terephthalate over Homogenous Catalysts
Korean Journal of Chemical Engineering(2024)
摘要
The vast amount of PET waste has made an enormous concern owing to its environmental pollution and human health effects. As an eco-friendly alternative option to treat plastic waste, this study investigated the transesterification of bis 2-hydroxyethyl terephthalate (BHET) into bis 4-hydroxybutyl terephthalate (BHBT) using 1, 4-butanediol (BDO) as a solvent in a typical batch reactor at various temperatures. Zinc acetate (Zn-A), antimony (III) oxide, tin (II) chloride, and titanium isopropoxide (Ti-IP) were utilized as catalysts. The effects of the experimental parameters, including the catalyst type, temperature, and catalyst loading, on the transesterification of BHET into BHBT were evaluated. Ti-IP and Zn-A showed higher catalytic activities than the other catalysts. Furthermore, Zn-A demonstrated to be a promising catalyst at lower temperatures, whereas Ti-IP exhibited higher activity at higher temperatures. An increase in temperature improved the yield of BHBT up to (0.99 mol/L) and showed the highest BHET conversion (98.93%) when Ti-IP was used as a catalyst at 210 °C. BHET conversion and the yield of BHBT were raised greatly when the catalyst amount was increased from 0.1 to 0.3 wt%. This study presents the transesterification of BHET using a Ti-IP catalyst as a novel technology for producing valuable BHBT for industrial applications.
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关键词
Transesterification,BHET,BHBT,BDO,Titanium isopropoxide
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