Acoustic Applications of a Foamed Geopolymeric-Architected Metamaterial

The paper compares and evaluates the influence of the presence of perforations on the sound absorption coefficient (SAC) of a negative stiffness metamaterial based on a foamed ceramic geopolymer. Chemical–physical, microstructural, dynamic–mechanical, and sound characterisations are presented. A rigid, lightweight geopolymeric porous material has been prepared using an inorganic/organic monomeric mixture containing oligomeric sialates and siloxanes foamed with aluminium powder. This process results in an amorphous rigid light foam with an apparent 180 Kg/m3 density and a 78% open-pore. The viscoelastic characterisation by dynamic mechanical analysis (DMA) carried out from 10−3 to 103 Hz indicates the behaviour of a mechanical metamaterial with negative stiffness enabling ultrahigh energy absorption at straining frequencies from 300 to 1000 Hz. The material loss factor (the ratio of dissipative/elastic shear moduli) is about 0.03 (essentially elastic behaviour) for frequencies up to 200 Hz to suddenly increase up to a value of six at 1000 Hz (highly dissipative behaviour). The corresponding storage and loss moduli were 8.2 MPa and 20 MPa, respectively. Impedance tube acoustic absorption measurements on perforated and unperforated specimens highlighted the role of perforation-resonant cavities in enhancing sound absorption efficiency, particularly within the specified frequency band where the mass of the negative stiffness foamed geopolymer matrix magnifies the dissipation effect. In the limits of a still exploratory and comparative study, we aimed to verify the technological transfer potentiality of using architected metamaterials in sustainable building practices.