Quadruple Control Electrochromic Devices Utilizing Ce4 W9 O33 Electrodes for Visible and Near-Infrared Transmission Intelligent Modulation.

Electrochromic smart windows are promising for building energy savings due to their dynamic regulation of the solar spectrum. Restricted by materials or traditional complementary device configuration, precisely and independently controlling of visible (VIS) and near-infrared (NIR) light is still on the drawing board. Herein, a novel Zn2+ electrochemically active Ce4 W9 O33 electrode is reported, which demonstrates three distinct states, including VIS and NIR transparent "bright and warm" state, VIS and NIR opaque "dark and cool" state, VIS transparent and NIR opaque "bright and cool" state. A dual-operation mode electrochromic platform is also presented by integrating Ce4 W9 O33 /NiO complementary device and Zn anode-based electrochromic device (Ce4 W9 O33 /Zn/NiO device). Such a platform enables an added VIS opaque and NIR transparent "dark and warm" state, thus realizing four color states through individually controlling Ce4 W9 O33 and NiO electrodes, respectively. These results present an effective approach for facilitating electrochromic windows more intelligent to weather/season conditions and personal preferences.