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Double loading of ZnCl2 by polytopic ligands which co-extract Zn2+ and tetrachloridozincate

Tsung‐I Lin,Vesna Gasperov,Kate Jennifer Smith,Christine C. Tong,Peter A. Tasker

Dalton Transactions（2010）

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Abstract
Combining cation- and anion-binding functionalities in a salen-type extractant leads to multiple loading of ZnCl2. Zn(II) cations are bound by the salen N2O22− donor set, and chlorozincate anions are associated with protonated pendant amine groups.
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Key words
zncl2,polytopic ligands,co-extract
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