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Terahertz crystal electric field transitions in a Kondo-lattice antiferromagnet

PHYSICAL REVIEW B(2024)

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Abstract
Hybridization between the localized f electrons and the delocalized conduction electrons together with the crystal electric field (CEF) play a determinant role in governing the many-body ground state of a correlatedelectron system. Here, we investigate the low-energy CEF states in CeAg2Ge2, a prototype Kondo-lattice antiferromagnet where Kondo correlation is found to exist within the antiferromagnetic phase. Using timedomain THz reflection spectroscopy, we show direct evidence of two low-energy CEF transitions at 0.6 THz (2.5 meV) and 2.1 THz (8.7 meV). The presence of low-frequency infrared-active phonon modes further manifests as a Fano-modified line shape of the 2.1 THz CEF conductivity peak. The temporal spectral weights obtained directly from the THz time traces, in addition, corroborate the corresponding CEF temperature scales of the compound.
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