Synergistic Electronic Interaction of Nitrogen Coordinated Fe-Sn Double-Atom Sites: An Efficient Electrocatalyst for Oxygen Reduction Reaction

Double-atom site catalysts (DASs) have emerged as a recent trend in the oxygen reduction reaction (ORR), thereby modifying the intermediate adsorption energies and increasing the activity. However, the lack of an efficient dual atom site to improve activity and durability has limited these catalysts from widespread application. Herein, the nitrogen-coordinated iron and tin-based DASs (Fe-Sn-N/C) catalyst are synthesized for ORR. This catalyst has a high activity with ORR half-wave potentials (E1/2) of 0.92 V in alkaline, which is higher than those of the state-of-the-art Pt/C (E1/2 = 0.83 V), Fe-N/C (E1/2 = 0.83 V), and Sn-N/C (E1/2 = 0.77 V). Scanning electron transmission microscopy analysis confirmed the atomically distributed Fe and Sn sites on the N-doped carbon network. X-ray absorption spectroscopy analysis revealed the charge transfer between Fe and Sn. Both experimental and theoretical results indicate that the Sn with Fe-NC (Fe-Sn-N/C) induces charge redistribution, weakening the binding strength of oxygenated intermediates and leading to improved ORR activity. This study provides the synergistic effects of DASs catalysts and addresses the impacts of P-block elements on d-block transition metals in ORR. This work introduces the Fe-Sn-NC dual-atom electrocatalyst, a breakthrough in oxygen reduction reaction (ORR). By synergizing d- and p-block metals (Fe and Sn), a unique strategy is employed, incorporating a single Sn atom to precisely control the intermediate adsorption energy on Fe-N-C. The resulting catalyst, Fe-Sn-NC, demonstrates exceptional activity and stability in acidic and alkaline conditions, presenting a promising advancement in electrocatalysis. image