Electro-catalytic ozonation of contaminants in landfill leachate: Optimization by BBD, Economic Evaluation, Mechanism, and Reaction Pathway

An electro-catalytic ozonation process with ZnO nano-granules as a catalyst (CFR-EC/O3-UV@ZnO process) was developed to treat raw landfill leachate. LC-MS analysis was applied to determine organic compounds. After CFR-EC/O3-UV@ZnO process, COD, TOC, BOD5, NH4+-N, P-PO4-3, color, and turbidity were reduced to 90.9, 89.4, 89.1, 89.5, 87.7, 99.1, and 99.7%, respectively under the optimum conditions of 10g.hr-1 O3 dosage, pH 11.0, and 0.006L.min-1 flowrate. At the same conditions removal efficiencies of heavy metals (HMs): Cr6+, Pb2+, As3+, Mg2+, B3+, Mn3+, Ni2+, Ba2+, Hg2+, Co2+, Fe2+, and Li+ were obtained 90, 84.7, 90, 99, 83.7, 95, 20, 75, 91, 90, 78 and 60%, respectively. In spite of high COD and BOD5 removal efficiencies, the process could not remove two organic substances including diphenylamine and 2,2,4-trimethyl-1,3-pentanediol. A high R2 value of 0.99 demonstrated the accuracy of the selected model. Economic evaluation depicted that the current process cost 0.95 $.m-3. Finally, this process is suggested for the treatment of landfill leachate with relatively high efficiency.