NO formation by N2/O2 plasma catalysis: The impact of surface reactions, gas-phase reactions, and mass transport
Chemical Engineering Journal（2024）
Abstract
•Silver catalyzes NO formation from plasma-derived N radicals with high selectivity.•Rates of N conversion to NO on the surface are determined by rates of mass transfer processes.•Consumption of N in the gas phase limits the ability of N to diffuse to the surface and react to form NO.
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Key words
Plasma catalysis,Molecular beam mass spectrometry,Nitrogen fixation,Radical chemistry,Reaction–diffusion
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