Boosting carrier separation and transport in CuGaO2 photocathodes by coupled effects of surface polarization and facet-junction

This study investigates the synergistic enhancement of carrier separation and transport in CuGaO2 photocathodes, achieved through the coupled effects of surface polarization and facet -junction engineering. Delafossite CuGaO2 microspheres, which exhibit a flower-like micro -nano hierarchical structure, are synthesized facilely through a one -pot hydrothermal process. These microspheres self -assemble from CuGaO2 nanosheets, driven by electrostatic forces among crystal facets. Morphology and size are systematically modulated by pH values, solvent composition, and reaction temperature. The CuGaO2 nanosheets, serving as fundamental building blocks, manifest notable surface polarization effects that facilitate the efficient transport of photo -generated carriers. The facet -junction formed between intersecting CuGaO2 nanosheets facilitates the collection of photo -generated electrons and holes on both sides of the interface, leading to spatial separation. Consequently, the CuGaO2 microspheres synergistically combine nanoscale surface polarization and microscale facet -junction effects, promoting the effective separation and rapid transport of electron -hole pairs generated under visible -light irradiation. The resulting simple bare photocathode, constructed using CuGaO2 microspheres, demonstrates a photocurrent density of 32 mu A/cm2 at zero -bias, with a peak incident photon -to -current efficiency of 12.72 % at a 450 nm wavelength. Further optimization of the CuGaO2 photocathode yields a better photocurrent density of 138 mu A/cm2 at 0.33 VRHE. These results underscore the significance of integrating nanoscale surface polarization effects with microscale facet -junction effects to achieve efficient separation and rapid transport of photogenerated carriers in photoelectrochemical cells.