Magnesite everywhere: Formation of carbonates in the alkaline lakes and playas of the Cariboo Plateau, British Columbia, Canada

The Cariboo Plateau in central British Columbia, Canada, hosts the largest aerial extent of low temperature lacustrine magnesite in the world. Magnesite was the most abundant carbonate mineral in 21 of 33 sampled alkaline lakes and 20 of 22 sampled playas. Calcite, hydromagnesite and very high magnesium calcite (VHMC, also called disordered dolomite) were also found in closed basin alkaline lakes on the plateau. Carbonate mineralogy was strongly associated with lake water geochemistry, particularly total alkalinity. VHMC was the dominant carbonate mineral in lakes with the highest alkalinities (>1000 mEq/kg), magnesite was the dominant carbonate mineral in lakes in the middle range of alkalinities (generally 70 to 800 mEq/kg) and hydromagnesite with minor amounts of magnesite was the phase assemblage in lakes with lower relative alkalinities (<110 mEq/kg). The geochemical trends for the activity of CO32-, Ca2+ and Mg2+ suggest that these constituents in all Cariboo water bodies are controlled by the precipitation of Ca- and/or Mg-carbonate minerals. The waters are near equilibrium with metastable crystalline Ca-carbonate and Mg-carbonate minerals. We hypothesize that carbonates present in the lakes likely formed via non-classical crystallization pathways based on the relationship between aqueous geochemistry and mineralogy and the chemical composition of the Ca-bearing magnesites. Non-classical crystallization offers new models for thinking about magnesite formation in lacustrine environments.