Analysis of compressive strength, durability properties, and micromechanisms of solidified loess using industrial solid waste: Slag-white mud-calcium carbide residue

Zhijia Xue,Ying Zhang, Jiang Luo,Changgen Yan, Musigiyimana Emmanuel, Xiaolong Jia

JOURNAL OF BUILDING ENGINEERING(2024)

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摘要
Traditional lime -solidified loess presents the issue of high carbon dioxide emissions. This paper presents the development of a kind of cementitious material using industrial solid waste: slag-white mud-CCR (calcium carbide residue). The slag mainly contains CaO, SiO2, and Al2O3, with a 10.6 pH value. The white mud and CCR mainly contain CaCO3 and Ca(OH)2, respectively. We further assessed the efficacy of slag-white mud-CCR in solidified loess and employed SEM and TG/DTG to explore their micromechanisms. The pH value of the CB4 sample (slag-white mud-CCR with the lowest CCR content) was 42.3 % higher than that of pure loess. Considering the 3 -day and 28 -day compressive strength and the material costs, the optimal mortar mixture ratio was found to be slag-white mud-CCR = 60:32:8, and this mixture was used to solidify loess. The unconfined compressive strength of 15 % slag-white mud-CCR-solidified loess is almost 5.0 times and 6.0 times higher than that of lime -solidified loess at 7 and 28 days of curing age, respectively. The durability of the solidified loess after freeze-thaw and wet-dry cycles was significantly improved compared with that of lime- or slag -solidified loess. Specifically, 10 % and 15 % slag-white mud-CCR-solidified loess maintained a high compressive strength after eight freeze-thaw and wet-dry cycles. SEM and TG/DTG analyses of the mortar and solidified loess confirmed the formation of hydration products of C-S-H- and C-A-(S)-H-type gels. The compressive strength results were obtained using a dual mechanism: the cementation of loess particles through the formation of hydration products and their subsequent filling action.
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关键词
Solidified loess,Durability,Slag-white mud-CCR,Compressive strength,Micromechanism
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