Macroscale preparation of CoS2 nanoparticles for ultra-high fast-charging performance in sodium-ion batteries

DALTON TRANSACTIONS(2024)

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摘要
Improving the fast-charging capabilities and energy storage capacity of electric vehicles presents a feasible strategy for mitigating the prevalent concern of range anxiety in the market. Nanostructure electrode materials play a crucial role in this process. However, the current method of preparation is arduous and yields restricted quantities. In view of this, we have devised an innovative approach that provides convenience and efficacy, facilitating the large-scale synthesis of CoS2 nanoparticles, which exhibited exceptional performance. When the current density was 1000 mA g(-1), the discharging capacity reached 760 mAh g(-1) after 400 cycles. Remarkably, even at an increased current density of 5000 mA g(-1), the discharging capacity of CoS2 remained at 685.5 mAh g(-1). The ultra-high performance could be attributed to the specific surface area, which minimized the diffusion distance of sodium-ions during the charging and discharging processes and mitigated the extent of structural damage. Our straightforward preparation techniques facilitate the mass production and present a novel approach for the development of cost-effective and high-performing anode materials for sodium-ion batteries.
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