Optimising anode supported BaZr1-xYxO3-δ electrolytes for solid oxide fuel cells: Microstructure, phase evolution and residual stresses analysis

Yttrium-doped BaZrO3 is a promising electrolyte for intermediate-temperature protonic ceramic fuel cells. In the anode-supported configuration, a slurry containing the electrolyte is deposited on the surface of a calcined porous anode and sintered. Differences in sintering behaviour and thermal expansion coefficients for the anode and electrolyte result in elastic residual stresses that can impact the long-term stability of the cell during cyclic operation.