Novel antimony phosphates with enlarged birefringence induced by lone pair cations
DALTON TRANSACTIONS(2024)
摘要
Phosphates, whose obvious disadvantage is the relatively small birefringence, can be overcome by the introduction of post-transition metal cations containing stereochemically active lone-pair electrons. In this paper, two new compounds were successfully explored in the A-Sb-P-O system, i.e. Cs2Sb3O(PO4)3 (CsSbPO) and (NH4)2Sb4O2(H2O)(PO4)2[PO3(OH)]2 (NH4SbPOH). Transmission spectra show that CsSbPO has a surprising transmission range with a UV cutoff edge of 213 nm. First-principles calculations show that both compounds have a wide band gap (5.02 eV for CsSbPO and 5.30 eV for NH4SbPOH) and enlarged birefringence (Delta n = 0.034@1064 nm for CsSbPO and Delta n = 0.045@1064 nm for NH4SbPOH). The results of real-space atom-cutting investigations show that the distorted [SbOx] polyhedra originating from the asymmetric lone pair electrons give the main contribution to the total birefringence and overcome the disadvantage of small birefringence of phosphates but maintain wide transition windows. Novel centrosymmetric compounds, Cs2Sb3O(PO4)3 and (NH4)2Sb4O2(H2O)(PO4)2[PO3(OH)]2, were successfully obtained. It is shown that the birefringence is significantly enhanced by the introduction of the Sb3+ cations, and still has a wide band gap.
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