High-substituted hydroxypropyl cellulose prepared by homogeneous method and its clouding and self-assembly behaviors
CARBOHYDRATE POLYMERS(2024)
Abstract
Hydroxypropyl cellulose (HPC) is a sustainable cellulose derivative valued for its excellent biocompatibility and solubility and is widely used in various fields. Recent scientific research on high-substituted HPC mainly focused on its efficient preparation and phase transition behavior. Herein, a novel strategy of high-substituted HPC synthesis was demonstrated by employing DMSO/TBAF3H(2)O as a cellulose solvent, exhibiting more efficiency than traditional approaches. High-substituted HPC prepared has remarkable thermal stability, exceptional hydrophilicity, and satisfactory solubility. Phase transition behavior of HPC with varying molar degrees of substitution (MS) was delved and a notable negative correlation between MS and cloud point temperature (T-CP), was revealed, particularly evident at an MS of 12.3, where the T-CP drops to 33 degrees C. Moreover, a unique self-assembly behavior featuring structural color and responsiveness to force in a solvent-free environment emerged when the MS exceeded 10.4. These insights comprehensively strengthen the understanding and knowledge of high-substituted HPC, simultaneously paving the way for further HPC investigation and exploitation.
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Key words
Cellulose derivative,High-substituted hydroxypropyl cellulose,Clouding behavior,Self-assembly
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