Dye-Sensitized Photocatalysis: Hydrogen Evolution and Alcohol-to-Aldehyde Oxidation without Sacrifical Electron Donor

There is a growing interest in developing dye-sensitized photocatalytic systems (DSPs) to produce molecular hydrogen (H2) as alternative energy source. To improve the sustainability of this technology, we replaced the sacrificial electron donor (SED), typically an expensive and polluting chemical, with an alcohol oxidation catalyst. This study demonstrates the firstdye-sensitized system using a diketopyrrolopyrrole dye covalently linked to 2,2,6,6-tetramethyl-1-piperidine-N-oxyl (TEMPO) based catalyst for simultaneous H2 evolution and alcohol-to-aldehyde transformation operating in water with visible irradiation. This study shows that a two-hole oxidation process such as TEMPO catalyzed alcohol oxidation is a viable reaction to couple with reduction reaction to eliminate SED and generate two added-value chemicals in dye-sensitized photocatalytic systems. image