Dual-outward contraction-induced construction of 2D hollow carbon superstructures

A novel dual-outward contraction mechanism is applied to construct 2D hollow carbon superstructures (HCSs) via pyrolysis of hybrid ZIF superstructures. One outward contraction stress is offered by the in situ formed thin carbon shell, while another originates from the interconnected facets of ZIF polyhedra within the ZIF superstructure. A highly developed 2D hollow carbon superstructure was fabricated by harnessing the synergy between Foutward1 and Foutward2.