Anti-electrostatic cation?-hole and cation?lp-hole interactions are stabilized via collective interactions

Collective interactions are a novel type of bond between metals and AX(3) fragments with an electropositive central atom, A, and electronegative X substituents. Here, using electrostatic potential maps and state-of-the-art bonding analysis tools we have shown that collective interactions are anti-electrostatic cation & ctdot;pi-Hole or cation & ctdot;lp-Hole interactions.