Probing the p-type Chemiresistive Response of NiFe₂O₄ Nanoparticles for Potential Utilization as Ethanol Sensor

Detection of gas molecules and volatile organic compounds (VOCs) using efficient, low cost sensors has fetched significant attention in environmental monitoring, safety measures and medical diagnosis. In the present work, nickel ferrite (NFO) nanoparticles are explored as p-type semiconducting metal oxide (SMO) sensor for detection of five different organic vapors namely methanol, ethanol, n-propanol, iso-propanol and acetone which often cause severe damage to human body under prolonged exposure. The sensing studies in presence of the aforementioned five vapors are carried out by varying the sensor operating temperature (225-300 degrees C) and vapor concentrations (10-1000 ppm). Developed NFO sensor demonstrated best performance in terms of sensing (similar to 10 ppm), response time (<10 s), excellent repeatability and selectivity towards ethanol among all other considered gas species. The repeatability of the sensor response is verified and the underlying reasons for the variation in the response of NFO sensor due to the change of operating temperature, analyte type and concentrations has been discussed. The synthesis of NFO through auto combustion method and study on their formation behaviour, oxygen vacancy evolution, band gap calculation, crystalline nature as well as microstructural features provides here the comprehensive information about the potential application of NFO nanoparticles as gas sensor.